![]() ![]() Ti(I) has been observed in (Ar = C6H5, p-C6H4F, 3,5-C6H3(CF3)2) see Fausto Calderazzo, Isabella Ferri, Guido Pampaloni, Ulli Englert, Malcolm L. ![]() Angewandte Chemie International Edition 56 (8): 2050–2053. "Solution Synthesis, Structure, and CO Reduction Reactivity of a Scandium(II) Complex". Sc(II) has been observed see Woen, David H."The First Example of a Formal Scandium(I) Complex: Synthesis and Molecular Structure of a 22-Electron Scandium Triple Decker Incorporating the Novel 1,3,5-Triphosphabenzene Ring". ![]() Journal of the American Chemical Society 132 (35): 12492–501. "Mechanistic Elucidation of the Formation of the Inverse Ca(I) Sandwich Complex and Stability of Aryl-Substituted Phenylcalcium Complexes".
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